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n -π Electron donor–acceptor complexes. III. Aliphatic amines with dicyanobenzenes. Electric and steric effects of the N -substituents on complex formation

✍ Scribed by Anunziata, Jorge D.; Galaverna, Norma S.; Singh, Joaquín O.; Silber, Juana J.


Book ID
127342788
Publisher
NRC Research Press
Year
1986
Tongue
French
Weight
328 KB
Volume
64
Category
Article
ISSN
0008-4042

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n—π electron-donor—acceptor complexes—IV
✍ M.A. Biasutti; J.D. Anunziata; J.J. Silber 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 381 KB

Abstmct-The stability constants (K) for the electron-donor-acceptor (EDA) complexes formed between aliphatic amines as n-donors and 1,3\_dicyanobenxene (1,3-DCB) have been determined in n-hexane as solvent. By means of free energy substitutent parameters and regression analysis, the electronic and s