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N-{(Z)-2-[1-(Triisopropylsilyl)-1H-indol-3-yl]-2-(triisopropylsilyloxy)vinyl}-2-(3,4,5-trimethoxyphenyl)acetamide

✍ Scribed by Peifer, Christian ;Selig, Roland ;Schollmeyer, Dieter ;Laufer, Stefan

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 336 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807006514

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✦ Synopsis

The molecular structure of the title compound, C~39~H~62~N~2~O~5~Si~2~, obtained as an unexpected side product, was determined in the course of our studies on the synthesis of N-triisopropyl-1__H__-indol-3-yl derivatives. Interestingly, although the triisopropylsilyl group was intended as a temporary protecting group, the compound comprises a remarkably stable N—Si bond. The vinyl C=C double bond possesses a Z configuration.

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✦ Synopsis

N-{(Z)-2-[1-(Triisopropylsilyl)-1H-indol-3-yl]-2-(triisopropylsilyloxy)vinyl}-2-(3,4,5-trimethoxyphenyl)acetamide