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N-Substituted 1-Aminoindoles from Electrogenerated N-Substituted 2-(ortho-Nitrosophenyl)ethylamines

✍ Scribed by B. A. Frontana-Uribe; C. Moinet; L. Toupet

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
281 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

An electrochemical methodology offering efficient access to mediates. Under slightly basic conditions, these undergo spontaneous ring-contraction to produce the N-substituted N-alkyl-and N-aryl-substituted 1-aminoindoles has been developed.

N-Substituted 2-(ortho-nitrosophenyl)ethyl-heterocycles in good yields. The reactions have been studied in slightly acidic and slightly basic aqueous alcoholic media. amines, electrogenerated in a "redox" flow cell, undergo intramolecular cyclization to hydrocinnoline-type interlibrium depends on the attached substituents. [10] This equi- [a] Laboratoire dЈElectrochimie et Organome ´talliques, UMR CNRS 6509, laboratory, whereby nitrosobenzenes can easily be prepared

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