๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

n-Propyldiazonium ion alkylates O6 of guanine with rearrangement, but alkylates N-7 without rearrangement

โœ Scribed by Scribner, John D.; Ford, George P.


Book ID
122493032
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
509 KB
Volume
16
Category
Article
ISSN
0304-3835

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Rearrangement of unactivated N-alkyl-O-b
โœ Andrew J Clark; Yassair S.S Al-Faiyz; Divya Patel; Michael J Broadhurst ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 72 KB

The phosphazene super bases BTPP 5, P-2-t Bu 6, and P-4-t Bu 7 mediate the rearrangement of unactivated N-alkyl-Obenzoyl hydroxamic acid derivatives 8, 11a-f, 13 and 16 to give 2-benzoyloxy amides 9, 12a-f, 14 and 17. The rate of reaction was found to be dependant upon the steric nature of the N-alk