n-Propyl gallate–dichloromethane (3/0.5)
✍ Scribed by Hitachi, Akio ;Makino, Takashi ;Iwata, Shohei ;Mizuguchi, Jin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 161 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
n-Propyl gallate (PG) is a charge-control agent used for toners in electrophotography, and shows pseudo-polymorphism. The title compound, 3C 10 H 12 O 5 Á0.5CH 2 Cl 2 , is isostructural with the corresponding chloroform solvate. The asymmetric unit is composed of three PG molecules and a half-molecule of dichloromethane, the solvent being disordered over an inversion centre. There are intra-and intermolecular O-HÁ Á ÁO hydrogen bonds, forming a two-dimensional hydrogenbond network in the (421) plane.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.050 wR factor = 0.157 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [CuCl~2~(C~31~H~28~N~6~)]·0.5C~2~H~3~N, the Cu^2+^ atom is coordinated in a distorted square-pyramidal geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by two chloride anions.