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N-phenylaminomethylation: A one-step route to N-substituted anilines from unsaturated fatty derivatives and olefins

✍ Scribed by Robert A. Grimm


Book ID
112777969
Publisher
Springer-Verlag
Year
1969
Tongue
English
Weight
437 KB
Volume
46
Category
Article
ISSN
0003-021X

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## Abstract The [4 + 2] cycloadditions of 2‐oxobut‐3‐enenitrile (1a), 2‐oxopent‐3‐enenitrile (1b), and ethyl 4‐cyano‐4‐oxobut‐2‐enoate (1c) with 1,3‐dimethyluracil (2), 1,3, 6‐trimethyluracil (9), or 1,3,5‐trimethyluracil (16) were investigated. The reactions of 1a with 2 or with 9 lead to bicyclic