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N-permethylation of polyamines at trace levels for gas chromatographic analysis

✍ Scribed by Marianne Dalene; Thomas Lundh; Lennart Mathiasson

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
507 KB
Volume
322
Category
Article
ISSN
1873-3778

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✦ Synopsis

A method for the trace analysis of polyamines is presented. It involves permethylation of the amines to the corresponding tertiary amines, extraction of the latter into an organic solvent and subsequent analysis by gas-liquid chromatography using nitrogen-selective detection.

The chromatographic behaviour was considerably improved compared with direct analysis of underivatized polyamines, and gave detection limits of the order of 0.1 ng/pl and linear calibration plots in the 0.1-100 ng range. Amines of interest from work environmental health aspects were included as model compounds.

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