✦ LIBER ✦

N-Hydroxypyridine-2-thione carbamates. VII. Intermolecular addition and addition-cyclization reactions of aminium cation radicals

✍ Scribed by Martin Newcomb; M. Udaya Kumar

Book ID: 104222119
Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 294 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88851-6

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✦ Synopsis

Dialkylaminium cation radicals pmduced from the title precursors add to ethyl vinyl ether to give &amino ethers in good yields. When an ally1 group is present on nitrogen, a cyclization reaction follows the addition, and pyrrolidines ate formed. Simple cyclic enol ethers also can be employed.

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