𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-Heterocyclic Carbenes for the Organocatalytic Ring-Opening Polymerization of ε-Caprolactone

✍ Scribed by Kamber, Nahrain E.; Jeong, Wonhee; Gonzalez, Silvia; Hedrick, James L.; Waymouth, Robert M.


Book ID
120356084
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
116 KB
Volume
42
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Lanthanide Thiolate Complexes: Novel Ini
✍ Hong-Mei Sun; Huan-Rong Li; Chang-Sheng Yao; Ying-Ming Yao; Hong-Ting Sheng; Qi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini