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N-Heterocyclic Carbenes: Exotic Molecules as Precursors to Unusual Hydrogen Bonds

✍ Scribed by Jonathan K. W. Chui; Taramatee Ramnial; Jason A. C. Clyburne


Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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Concave Imidazolinium Salts as Precursor
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## Abstract Concave bimacrocyclic imidazolinium ions **8** have been synthesized as precursors for N‐heterocyclic carbenes **9** (NHC) in 13 to 29 % overall yields based on 2‐nitroresorcinol (**1**). As bridgeheads, 2,6‐bis(ω‐alkenyloxy)anilines **3** have been synthesized from **1**. Reaction of *