𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-Ethyl­ethanaminium 3,5,6-trichloro­pyridin-2-olate

✍ Scribed by Zheng, Hui ;Liu, Yun-Kui ;Xu, Dan-Qian ;Xu, Zhen-Yuan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
128 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title salt, C~4~H~12~N^+^·C~5~HCl~3~NO^−^, the non-H atoms of the cation are essentially coplanar. Intermolecular N—H...O hydrogen bonds link two cations and two anions into a centrosymmetric cluster. The crystal packing is further stabilized by van der Waals forces.

📜 SIMILAR VOLUMES

Adducts of 2,5,6-trichloro-3,4-pyridine
Adducts of 2,5,6-trichloro-3,4-pyridine with aromatic hydrocarbons
✍ J.D. Cook; B.J. Wakefield 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 154 KB

The recent report (1) that derivatives of 2,5,6-trifluoro-3,4-pyridyne could not bs obtained by the decomposition of 2,3,5,6-tetrafluoro~pyridyl-lithium in the presence of fursn and other aryne traps prompts us to publish the results of our experiments on related chloro-compounds.

(E)-N2-{3-[(6-Chloro­pyridin-3-yl)meth­y
(E)-N2-{3-[(6-Chloro­pyridin-3-yl)meth­yl]-5-cyano-3H-1,2,3-triazol-4-yl}-N1,N1-bis­(2-hydroxy­ethyl)formamidine
✍ Chen, Xiao-Bao ;Shi, De-Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 357 KB

In the title compound, C 14 H 16 ClN 7 O 2 , the triazole ring carries cyano and formamidine substituents and is bound via a methylene bridge to a chloropyridine unit. There is evidence of significant electron delocalization in the triazolyl system. Intramolecular O-HÁ Á ÁO and intermolecular C-HÁ Á