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N-Boc-3-trichloromethyloxaziridine: a new, powerful reagent for electrophilic amination

✍ Scribed by Joe¨lle Vidal; Jean-Christophe Hannachi; Gwe´nae¨lle Hourdin; Jean-Christophe Mulatier; Andre´ Collet

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
252 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The aza-Wittig reaction of Ph3P=N-Boc with chloral, followed by the oxone oxidation of the resulting imine, afforded N-Boc-3-trichloromethyloxaziridine in excellent yield. This new oxaziridine proved to be a powerful electrophilic amination reagent.

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