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N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes

✍ Scribed by Wang, Aichen; Sun, Hongjian; Li, Xiaoyan

Book ID
121223575
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
119 KB
Volume
27
Category
Article
ISSN
0276-7333

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✍ Chul-Ho Jun; Choong Woon Moon; Hyuk Lee; Dae-Yon Lee 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 207 KB

Herein described is the chelation-assisted C-C bond activation of unstrained ketones under the co-catalyst system of Rh(PPh 3 ) 3 Cl and 2-amino-3-picoline (1). This reaction is based on the strategy we recently developed in hydroacylation with aldehydes in which 2-aminopyridine derivatives function