N-Arylation and N,N-Dibenzylation of Coordinated N2 with Organic Halides; Differences in the Reactivity of trans-[Mo(N2)2(Me8[16]aneS4)] and Its Phosphane Analogues

✍ Scribed by Prof. Dr. Toshikatsu Yoshida; Tomohiro Adachi; Tatsuo Ueda; Manabu Kaminaka; Nobuyoshi Sasaki; Prof. Dr. Taiichi Higuchi; Takayuki Aoshima; Izumi Mega; Dr. Yasushi Mizobe; Prof. Dr. Masanobu Hidai

• Publisher: John Wiley and Sons
• Year: 1989
• Tongue: English
• Weight: 379 KB
• Volume: 28
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198910401

✦ Synopsis

benzene gave orange crystals. M.p. 181 -185°C (decomp.); yield: 234.8 mg (70%).

4:

A vigorously stirred solution of l(200 mg, 0.34 mmol) in toluene (10 ml) was treated with solid [Pt(PPh,),(C,H,),] (241.9 mg, 0.34 mmol) at 0°C. Upon addition, the solution immediately turned deep brown. After the solution was allowed to warm lo 25 "C and stirred for 2 h the solvent was removed in vacuo. The resulting brown oil was redissolved in benzene (3 ml) and 4 crystallized after 2-8 h as a yellow solid. M.p. 188-194°C (decomp.); yield: 330.6mg (74%).