𝔖 Bobbio Scriptorium
✦   LIBER   ✦

N-Arylamides from Selenium-Catalyzed Reactions of Nitroaromatics and Amides in the Presence of Carbon Monoxide and Mixed Organic Bases

✍ Scribed by Jinzhu Chen; Gang Ling; Zhengkun Yu; Sizhong Wu; Xiaodan Zhao; Xiaowei Wu; Shiwei Lu

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
115 KB
Volume
346
Category
Article
ISSN
1615-4150

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

N‐Arylamides were exclusively obtained in moderate to good yields from selenium‐catalyzed reactions of nitroaromatics with amides in the presence of CO and mixed organic bases Et~3~N and DBU.

📜 SIMILAR VOLUMES

Highly Efficient Route to Diselenides fr
Highly Efficient Route to Diselenides from the Reactions of Imines and Selenium in the Presence of Carbon Monoxide and Water
✍ Xiaodan Zhao; Zhengkun Yu; Fanlong Zeng; Jinzhu Chen; Xiaowei Wu; Sizhong Wu; We 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 199 KB 👁 1 views

## Abstract Reactions of selenium with imines (RR^1^CNR^2^) of aldehydes and ketones in the presence of carbon monoxide, water and triethylamine lead to reductive selenation, on aerobic work‐up, to afford symmetrical diselenides (RR^1^CHSe)~2~ in good to excellent yields. The proposed mechanism su