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N-alkylation of 4-chloro-5-cyano-1,2,3-triazole with orthoformic acid derivatives

โœ Scribed by Yu. N. Bulychev; M. N. Preobrazhenskaya; A. I. Chernyshev; S. E. Esipov


Publisher
Springer US
Year
1988
Tongue
English
Weight
325 KB
Volume
24
Category
Article
ISSN
0009-3122

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(E)-N2-{3-[(6-Chloroยญpyridin-3-yl)methยญy
โœ Chen, Xiao-Bao ;Shi, De-Qing ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 357 KB

In the title compound, C 14 H 16 ClN 7 O 2 , the triazole ring carries cyano and formamidine substituents and is bound via a methylene bridge to a chloropyridine unit. There is evidence of significant electron delocalization in the triazolyl system. Intramolecular O-Hร ร รO and intermolecular C-Hร ร