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N-Alkyl-4-boronopyridinium Salts as Thermally Stable and Reusable Amide Condensation Catalysts.

โœ Scribed by Toshikatsu Maki; Kazuaki Ishihara; Hisashi Yamamoto


Book ID
101981951
Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

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N-alkyl-4-(Nโ€ฒ,Nโ€ฒ-dialkylamino)pyridinium
โœ D.J. Brunelle; Daniel A. Singleton ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

N-Alkyl salts of 4-dialkylaminopyridines are effective phase transfer catalysts which are up to 100 times more stable than tetrabutylammonium bromide to conditions encountered in nucleophilic aromatic substitution reactions. These salts are thermally stable to over 300ยฐC, and promote reactions in no