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N-Alkoxyacrylamides as Substrates for Enantioselective Diels—Alder Reactions.

✍ Scribed by Olivier Corminboeuf; Philippe Renaud

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

Polymer-supported chiral diol as ligand
Polymer-supported chiral diol as ligand of Ti(IV) for enantioselective Diels-Alder reaction
✍ José Irurre; Anna Fernández-Serrat; Francesc Rosanas 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB

The synthesis of the first polymer-supported TADDOL is reported. Its efficiency as chiral ligand of Ti(IV) was studied in the Diels-Alder cycloaddition of cyclopentadiene to 3-crotonoyl-1,3-oxazolidin-2-one, and was superior to that observed for its homogeneous equivalent, (4R,5R)-␣,␣,␣Ј,␣Ј-2-pentap