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N-alkoxy-N-acylnitrenium ions as possible intermediates in intramolecular aromatic substitution: novel formation of N-acyl-3,4-dihydro-1H-2,1-benzoxazines and N-acyl-4,5-dihydro-1H,3H-2.1-benzoxazepine

✍ Scribed by Glover, Stephen A.; Goosen, Andr�; McCleland, Cedric W.; Schoonraad, Johan L.


Book ID
118252325
Publisher
Royal Society of Chemistry
Year
1984
Weight
916 KB
Category
Article
ISSN
1472-7781

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## Abstract New procedures are described for the synthesis of α,β‐ethylenic and acetylenic aldehydes from 2‐butene‐ and 2‐butyne‐1,4‐diol, respectively (see __Scheme 1__). These are applied to the preparation of a particular δ‐acetylamino‐α,β‐ethylenic aldehyde ((__E__)‐**5**) as well as of its ace