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N-acryloyldibenz [b,f] azepine – a new monomer for the synthesis of photocrosslinkable copolymers

✍ Scribed by P. Hyde; L. J. Kricka; A. Ledwith

Publisher
Wiley (John Wiley & Sons)
Year
1973
Tongue
English
Weight
210 KB
Volume
11
Category
Article
ISSN
0887-6258

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📜 SIMILAR VOLUMES

Synthesis and reactions of polymers with
Synthesis and reactions of polymers with photoactive terminal groups—3. The use of radical promoted cationic polymerization for the synthesis of poly(n-butyl vinylether) with n-acyl dibenz(b, f)azepine terminal units
✍ Yusuf Yagci; Wolfram Schnabel; Anthony Ledwith 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 252 KB

The free radical promoted cationic polymerization of n-butyl vinyl-ether (BVE) was achieved by the thermal decompositon of N-[4,4-azobis-(4-cyanopentanoyl)]-bisdibenz(b, f)azepine (ADBA) in the presence of diphenyliodonium hexafluorophosphate (Ph2I+PF6) or silver hexafluorophosphate (AgPF6). Polymer

Synthesis and reactions of polymers with
Synthesis and reactions of polymers with photoactive terminal groups—4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units
✍ Yusuf Yagci; Metin Hayri Acar; Anthony Ledwith 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 221 KB

N-chlorocarbonyl dibenz[b,f] azepine in conjunction with AgSbF6 initiated the cationic polymerization of c(-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene so