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N-(4-Amino­benz­yl)-N,4-dimethyl­benzene­sulfonamide

✍ Scribed by Shi, Ming-Wang ;Chen, Xi-Ling ;Lang, J.-F. ;Wang, J.-H.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
226 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 15 H 18 N 2 O 2 S, the angle between the two benzene rings is 96.3 (3) A ˚. In the crystal structure, molecules are linked via intermolecular N-HÁ Á ÁO and C-HÁ Á ÁO interactions.

📜 SIMILAR VOLUMES

N-[4-(Dimethyl­amino)benzyl­idene]-4-met
N-[4-(Dimethyl­amino)benzyl­idene]-4-methyl­benzene­sulfonamide
✍ Deng, Li-Ping ;Hu, Yong-Zhou 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 117 KB

The molecule of the title compound, C 16 H 18 N 2 O 2 S, consists of essentially planar 4-(dimethylamino)benzylidene and 4-tolyl fragments bonded through a sulfone S atom, which is approximately coplanar with both fragments. The mean planes of the MeC 6 H 4 S and Me 2 NC 6 H 4 CH NS groups are rough

4-Amino-N-(2,3-dichloro­phen­yl)benzene­
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In the crystal structure of the title compound, C 12 H 10 Cl 2 N 2 O 2 S, there are two independent molecules in the asymmetric unit. Hydrogen bonds between NH 2 and SO 2 groups link molecules into layers, which interact with each other only by van der Waals forces

4-Amino-N-(2,5-dichloro­phen­yl)benzene­
4-Amino-N-(2,5-dichloro­phen­yl)benzene­sulfonamide
✍ Perlovich, German L. ;Tkachev, Valery V. ;Kazachenko, Vladimir P. ;Raevsky, Oleg 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 341 KB

The title compound, C~12~H~10~Cl~2~N~2~O~2~S, was crystallized from a water–ethanol mixture. The dihedral angle between the two benzene rings is 64.86 (11)°. N—H...O and N—H...N hydrogen bonds between the NH~2~ and SO~2~ groups link molecules into layers.

1,4-Bis{N-[4-(ethoxy­carbon­yl)benz­yl]-
1,4-Bis{N-[4-(ethoxy­carbon­yl)benz­yl]-N-(4-tolyl­sulfon­yl)amino­meth­yl}benzene
✍ Nieger, Martin ;Schwierz, Holger ;Vögtle, Fritz 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

The title compound, C 42 H 44 N 2 O 8 S 2 , features a molecular thread. The molecules have crystallographic C i symmetry. The crystal packing shows staples stabilized by weak C-HÁ Á ÁO interactions.

N-(4-Chloro­phen­yl)benzene­sulfonamide
N-(4-Chloro­phen­yl)benzene­sulfonamide
✍ Perlovich, German L. ;Tkachev, Valery V. ;Schaper, Klaus-Jürgen ;Raevsky, Oleg A 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 215 KB
4-n-Propyl-N-(8-quinol­yl)benzene­sulfon
4-n-Propyl-N-(8-quinol­yl)benzene­sulfonamide
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Silva, Luciano Luiz ;Foro, Sabi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

In the title compound, C 18 H 18 N 2 O 2 S, the torsion angle about the N-S bond between the quinoline ring system and the benzene ring is À60.9 (2) . The NH group forms an intramolecular hydrogen bond to the quinoline N atom.