N-(3-Fluorophenyl)-9H-xanthen-9-ylideneamine
✍ Scribed by Chopra, Deepak ;Nagarajan, K. ;Guru Row, T. N.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 149 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 19 H 12 FNO, the dihedral angle between the mean planes of the 9H-xanthene moiety and the 3-¯uorophenyl group is 82.5 ( 1) . An intramolecular CÐ HÁ Á Á% interaction stabilizes the molecular conformation.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.002 A Ê R factor = 0.042 wR factor = 0.115 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 23 H 28 N 2 O 2 , the pyran ring in the xanthene moiety adopts a half-chair conformation. The molecular structure is in¯uenced by intramolecular NÐ HÁ Á ÁN and CÐHÁ Á ÁO hydrogen bonds and the crystal structure is stabilized by CÐHÁ Á ÁO and CÐHÁ Á Á% interactions.
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.002 A Ê R factor = 0.054 wR factor = 0.147 Data-to-parameter ratio = 18.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract A new monoxanthen‒9‒yl derivative of urea has been synthesized and the structure of this product (__N__‒9 __H__‒xanthen‒9‒ylurea) and that of the previously known __N__,__N__′‒di‒9 __H__‒xanthen‒9‒ylurea have been proved by ^15^N NMR and other spectroscopic techniques. A series of ^13^C