The structure of the phenanthroline-derived viologen, C 26 H 22 N 2 2+ Á2Br À ÁCH 3 OH, as the methanol solvate, was determined as part of a ¯uorescence-quenching study. There is intermolecular %±% stacking of the phenanthroline and benzyl arms as well as methanol hydrogen bonding to a bromide.
✦ LIBER ✦
N-[2-(Hydroxymethoxyboryl)benzyl]-4,7-phenanthrolinium bromide methanol solvate
✍ Scribed by Olmstead, Marilyn M. ;Suri, Jeff T. ;Singaram, Bakthan
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 247 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 90 K Mean '(C±C) = 0.005 A Ê R factor = 0.042 wR factor = 0.096 Data-to-parameter ratio = 13.9
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
N,N′-Dibenzyl-4,7-phenanthrolinium dibr
✍
Olmstead, Marilyn M. ;Suri, Jeff T. ;Singaram, Bakthan
📂
Article
📅
2004
🏛
International Union of Crystallography
🌐
English
⚖ 301 KB
N—H⋯N hydrogen bonds in trimethoprim sa
✍
Panneerselvam, Pathus ;Stanley, Nithianantham ;Muthiah, Packianathan Thomas
📂
Article
📅
2002
🏛
International Union of Crystallography
🌐
English
⚖ 219 KB
N-[4-(2-Oxo-2H-chromen-3-yl)-3-phenyl-3H
✍
Seethalakshmi, T. ;Rajeswar Rao, V. ;Vijaya Kumar, P. ;Kaliannan, P.
📂
Article
📅
2006
🏛
International Union of Crystallography
🌐
English
⚖ 265 KB
In the title structure, C 24 H 17 N 2 O 2 S + ÁBr À ÁCH 3 OH, the cations, anions and solvent molecules form centrosymmetric clusters via a combination of intermolecular N-HÁ Á ÁO, O-HÁ Á ÁBr and C-HÁ Á ÁBr interactions.