In the title compound, C 12 H 9 BrN 2 O, (I), the pyridyl and bromophenyl rings are almost coplanar. There is an intramolecular NÐHÁ Á ÁN hydrogen bond between the pyridine N atom and the amide N atom [NÁ Á ÁN = 2.657 (3) A Ê and NÐ HÁ Á ÁN = 112.6 ].
N-(2-Bromophenyl)pyridine-3-carboxamide
✍ Scribed by Percival, Darryl ;Storey, John M. D. ;Harrison, William T. A.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 219 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 12 H 9 BrN 2 O, the molecules assemble into C(4) chains in the crystal structure by way of N-HÁ Á ÁO bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 90 K Mean (C-C) = 0.003 A R factor = 0.045 wR factor = 0.112 Data-to-parameter ratio = 15.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 9 H 10 BrNO, posseses normal geometrical parameters. The crystal packing is influenced by an N-HÁ Á ÁO hydrogen bond.
In the title compound, C 13 H 11 BrN 2 O, the molecules assemble into C(7) chains in the crystal structure by way of a weak C-HÁ Á ÁO interaction.