N-[2-(Aminocarbonyl)phenyl]-4-hydroxy-2-methyl-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide dimethyl sulfoxide solvate
✍ Scribed by Zia-ur-Rehman, Muhammad ;Choudary, Jamil Anwar ;Elsegood, Mark R. J. ;Siddiqui, Hamid Latif ;Ahmad, Saeed
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 206 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 17 H 15 N 3 O 5 SÁC 2 H 6 OS, the thiazine ring adopts a distorted half-chair conformation. The enolic H atom is involved in both intramolecular and intermolecular O-HÁ Á ÁO hydrogen bonds, the latter linking the molecules into centrosymmetric pairs. Both anthranilamide H atoms are involved in hydrogen bonding to O atoms of dimethyl sulfoxide molecules, linking the pairs of molecules into chains.
📜 SIMILAR VOLUMES
The title compound, C 25 H 28 N 4 O 4 , was synthesized by the reaction of methyl 2-{[3-(2-methylphenyl)-1,2,4-oxadiazol-5yl]methoxy}phenyl acetate and N,N-dimethylformamide dimethyl acetal. In the crystal structure, there are intramolecular C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds and intermolecular
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.003 A R factor = 0.029 wR factor = 0.072 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 24 H 25 ClN 4 O 4 , was obtained from the reaction of methyl 2-{[3-(2-bromophenyl)-1,2,4-oxadiazol-5yl]methoxy}phenylacetate with N,N-dimethylformamide dimethyl acetal. The molecules interact through weak C-HÁ Á ÁO intermolecular hydrogen bonds to form a zigzag chain parallel t