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Mössbauer studies of Fe(II) and Fe(III) chelates of some 2-hydroxy-1, 4-naphthoquinones

✍ Scribed by Clausius G. de Lima; F. Flávio; T. de Araujo; Ann DuFresne; Jens M. Knudsen


Publisher
Elsevier Science
Year
1971
Weight
180 KB
Volume
7
Category
Article
ISSN
0020-1650

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Fe hlijssbauer spectra (300 and 4.2"Kl h:lve been determined I"OI dioxidized [Fc(lII)Fe(IIl)] b~&rrocenylent'; rt large quadrupole splitting (2.S9 mm/see at 300°K) was interpreted in tern-s of cxtensivc dclocdlization of e~c ekerrons resultant from an Fe-Fe bonciing inrcraction. Mijssbnuer and elect