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Mössbauer spectroscopic studies of the disintegration of hexavalent iron compounds (BaFeO4 and K2FeO4)

✍ Scribed by I. Nowik; R.H. Herber; M. Koltypin; D. Aurbach; S. Licht

Book ID: 108190078
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 295 KB
Volume: 66
Category: Article
ISSN: 0022-3697
DOI: 10.1016/j.jpcs.2005.03.008

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The alkali sodium ferrate (IV) Na 4 FeO 4 has been prepared by solid-state reaction of sodium peroxide Na 2 O 2 and wustite Fe 1؊x O, in a molar ratio Na/Fe‫,4؍‬ at 4003C under vacuum. Powder X-ray and neutron di4raction studies indicate that Na 4 FeO 4 crystallizes in the triclinic system P؊1 with