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Mössbauer quadrupole splitting for57Fe in hemin peptides containing histidine

✍ Scribed by R. É. Garibov; V. I. Khleskov; A. I. Lumpov

Book ID
112378321
Publisher
Springer
Year
1984
Tongue
English
Weight
423 KB
Volume
20
Category
Article
ISSN
0040-5760

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An extremely large 57Fe Mössbauer quadru
An extremely large 57Fe Mössbauer quadrupole splitting for a distorted tetrahedral high-spin iron(II) complex
✍ David J. Evans 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 158 KB

The zero-field, solid state, 57Fe M~3ssbauer spectrum of the trinuclear high-spin iron(II) complex [Fe3(SC6H2~Pr3 -2,4,6)4{N(SiMe3)2} 2 ] has been recorded at 77 K. 'Unusually' large quadrupole splitting values (> 3.5 mm s -~) are observed for both the distorted trigonal planar (3.60 mm s-J) and dis