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Mössbauer, infrared and magnetic studies of nitrosobenzenepentacyanoferrate (Baudisch complex)

✍ Scribed by I. Dézsi; B. Molnár; T. Szalay; I. Jászberényi

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
306 KB
Volume
18
Category
Article
ISSN
0009-2614

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✦ Synopsis

Chemical analysis ofthc nitrosobenzenepentacyanoferrate complex pave a composition Na3Fc(CN)SNCCdIs -2HzO. Structural studies showed that the electronic structure of the iron is very similar to that in sodium nitroprusside.

The cffectivc number of iron d-electrons proved to be 0.12 more than in sodium nitroprusside p!bnbly as the result of clectmn donation by the benzene ring to the NO group.

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