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Mössbauer and EPR Study of Reaction Intermediates of Cytochrome P450

✍ Scribed by V. Schünemann; A. X. Trautwein; C. Jung; J. Terner

Book ID
110406164
Publisher
Springer
Year
2002
Tongue
English
Weight
74 KB
Volume
141/142
Category
Article
ISSN
0304-3843

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## It is believed by analogy to chloroperoxidase (CPO) from Caldariomyces fumago that the electronic structure of the intermediate iron-oxo species in the catalytic cycle of nitric oxide synthase (NOS) corresponds to an iron(IV) porphyrin-p -cation radical. Such species can also be produced by the