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Mössbauer and Electron Paramagnetic Resonance Studies of the Cytochrome bf Complex †

✍ Scribed by Schünemann, Volker; Trautwein, Alfred X.; Illerhaus, Jürgen; Haehnel, Wolfgang

Book ID
124062322
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
181 KB
Volume
38
Category
Article
ISSN
0006-2960

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✍ Jay L. Zweier; Abraham Levy 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 812 KB

## Abstract EPR and Mössbauer studies demonstrate that iron chelation by adriamycin is complex, with several different chelation structures. At physiological pH in aqueous solution, three different EPR spectra are observed: a spectrum at __g__ = 4.2 of Fe^3+^ in a rhombic crystal field (type 1); a