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Mutual solubility and bulk copolymerization of vinyl monomers with N-substituted maleimide

✍ Scribed by Guo-Rong Shan; Zhi-Xue Weng; Zhi-Ming Huang; Zu-Ren Pan

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 190 KB
Volume: 73
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19990923)73:13<2641::aid-app12>3.0.co;2-m

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✦ Synopsis

On the basis of the structure and melting parameters of N-substituted maleimide and vinyl monomer, the saturated molar solubility fraction of N-substituted maleimide in vinyl monomer or their mixtures was predicted. The predicted value was consistent with the experimental data. The effects of reaction temperature, initiator concentration, molar fraction of monomer, and monomer feed mode on the copolymerization rate of styrene (St)/N-phenylmaleimide (PMI) were studied. The bulk copolymerization kinetics of methyl methacrylate (MMA)/N-cyclohexylmaleimide, St/PMI/ MMA, and St/PMI/acrylonitrile were also investigated.

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