## Abstract In this paper we examine a series of hydrocarbons with structural features which cause a weakening of the Cο£ΏH bond. We use theoretical calculations to explore whether the carbonβcentered radicals R^β’^ which are created after breaking the bond can be stabilized enough so that they resist
Mutual Effect of Functional Groups and the Radical Center on the Reactivity of Nitroxyl Radicals
β Scribed by A. D. Malievskii; A. B. Shapiro
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Five aryl-substituted phenacetyl radicals (X = p-MeO, p-Me, H, p-Cl, p-CF 3 ) were generated by laser photolysis of the corresponding dibenzyl ketones in n-hexane and acetonitrile. The decarbonylation reaction was monitored through the rise in time-resolved absorption of the benzyl radical chromopho
Delayed hypersensitivity to DNCB and the inflammatory response to croton oil were evaluated in 144 and 121 patients respectively, prior to and 3 to 6 months following curative radiotherapy. Eighty-one patients had in vitro lymphocyte transformation by PHA; 59 (41%) were nonreactors to DNCB and 27 (2