Multiple-Time Correlation Functions in Spin-3/2 Solid-State NMR Spectroscopy
✍ Scribed by Roland Böhmer
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 148 KB
- Volume
- 147
- Category
- Article
- ISSN
- 1090-7807
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✦ Synopsis
Stimulated echo spectroscopy of nonselectively excitable I = 3/2 nuclei offers new perspectives for the investigation of ultraslow motions predominantly in inorganic solids and solid-like materials. Conditions for the generation of pure, quadrupole modulated multipolar spin orders and for the detection of two- and four-time correlation functions are discussed. The case of spins I > 3/2 is also briefly considered. Copyright 2000 Academic Press.
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## Abstract The ^31^P chemical shift (CS) tensors of the 1,3,2‐diazaphospholenium cation **1** and the __P__‐chloro‐1,3,2‐diazaphospholenes **2** and **3** and the ^31^P and ^19^F CS tensors of the __P__‐fluoro‐1,3,2‐diazaphospholene **4** were characterized by solid‐state ^31^P and ^19^F NMR studi