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Multiple-quantum artifacts in single-quantum two-dimensional correlated NMR spectra of strongly coupled spins

✍ Scribed by N. Murali; Ami Kumar

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
350 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis

Artifacts in the form of cross peaks have been observed along two-and three-quantum diagonals in single-quantum two-dimensional correlated (COW) spectra of several peptides and oligonucleotides. These have been identified as due to the presence of a non-equilibrium state of kind I (a state describable by populations which differ from equilibrium) of strongly coupled spins carried over from one experiment to the next in the COSY algorithm.

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