Multiple melting endotherms in isothermally melt-crystallized poly(butylene terephthalate)

✍ Scribed by Hong Gyun Kim; Richard E. Robertson

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 245 KB
• Volume: 36
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19980730)36:10<1757::aid-polb17>3.0.co;2-8

✦ Synopsis

The melting behavior of poly(butylene terephthalate) crystallized isothermally for various times was examined using differential scanning calorimetry. After short crystallization times, the DSC analysis gave two melting peaks, but after longer times, the analysis gave three peaks. The latter triplet of DSC peaks can be denoted as low, middle, and high, starting with the lowest temperature endotherm. The DSC peaks were simulated using a measured recrystallization rate and behavior for PBT and an assumed initial melting point distribution. The low and middle peaks represent the original melting peaks arising from isothermal crystallization. The high melting peak arises from recrystallization during the DSC heating scan.