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Multiple Diastereomers of [Mn+(αm-P2W17O61)2](20−n)−(M=UIV, ThIV, CeIII;m=1, 2).Syn- andAnti-Conformations of the Polytungstate Ligands in α1α1, α1α2, and α2α2Complexes

✍ Scribed by Angelo Ostuni; Robert E. Bachman; Michael T. Pope

Book ID
111592006
Publisher
Springer
Year
2003
Tongue
English
Weight
400 KB
Volume
14
Category
Article
ISSN
1040-7278

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Structure and Reactivity Studies on Dinu
Structure and Reactivity Studies on Dinuclear Copper Complexes of the Ligand α,α′-Bis{bis[1-(1′-methyl-2′-benzimidazolyl)methyl]amino}-m-xylene
✍ Giuseppe Battaini; Luigi Casella; Michele Gullotti; Enrico Monzani; Giorgio Nard 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

## Abstract The ligand α,α′‐bis{bis[1‐(1′‐methyl‐2′‐benzimidazolyl)methyl]amino}‐__m__‐xylene (L‐55) forms the complexes [Cu^I^~2~(L‐55)(MeCN)~2~](PF~6~)~2~ (1) and [Cu^II^~2~(L‐55)(OMe)~2~][ClO~4~]~2~ (2), in which an extremely weak axial amine interaction is imposed by the small five‐membered ben