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Multiphoton transitions in trans-butadiene observed by multiphoton ionization and thermal lensing spectroscopy

✍ Scribed by Veronica Vaida; Robert E. Turner; John L. Casey; Steven D. Colson


Book ID
103021633
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
416 KB
Volume
54
Category
Article
ISSN
0009-2614

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✦ Synopsis


The low-lymg two-photon states of trans-butadiene arc mvestigated using thermal lencing and multlphoton iomzation techniques.

For the first time, the termal lensing method IS applied to the study of B gas-phase multlphoton spectrum. This spectrum is compared with those obtained by multiphoton romzation and liqurd-phase thermal Icnsin_r spectroscopy.


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The (Z]"ll,+x 'z transition of Cs2 is observed in a very cold pulsed molecular beam using the resonanceenhanced twophoton ionization method. The term values ofthe substates of (2)'l&state are determined tobe T,= 14121.OkO. 1,14013.2 f 0.1, 13912.9+0. I, and 13909.4f 0.1 cm-' for the 2, l,, O,+, and