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Multiphoton dissociation: A maximum entropy formalism with mechanistic constraints and applications to alkyl iodides

✍ Scribed by J. Silberstein; R.D. Levine


Book ID
103022183
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
623 KB
Volume
99
Category
Article
ISSN
0009-2614

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✦ Synopsis


The relative importance of the different possible fragmentation pathways in multiphoton ionization-fmgmentation is determined by a maxlmum entropy formalism. Absorption by fragment ions Is allowed for, and leads to si_grlfrcantly lower temperatures. Differences between electron impact and laser-induced mass spectra are possibly due to the absence of secondary absorption in the former.