Multiphoton decomposition of 10BCl3 and 11BCl3 by CO2 TEA laser
β Scribed by Yo-ichi Ishikawa; Osamu Kurihara; Ryohei Nakane; Shigeyoshi Arai
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 514 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
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## Octafluorocyclobutane has been shown to decompose clearly to tetrafluoroethylene when irmdidted at room temperature with 949 cm-' radiation from a pulsed CO2 laser. A calculation of the energy absorbed from the laser beam. combined with known unimolecular sate constants for the corre~on~mg ther
UFs undergoes decomposition m the presence of SF6 when mixtures of both are madiated wrth a TEA CO2 laser. The mechanism for UFe decomposition may involve vrbrational energy transfer from excited SF, and laser absorption from the same laser pulse by excited UFe in its vibrational quasi-continuum \*