Heck reactions using water-soluble metal
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Bhalchandra M. Bhanage; Yutaka Ikushima; Masayuki Shirai; Masahiko Arai
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Article
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1999
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Elsevier Science
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French
โ 262 KB
Heck vinylation reaction was studied using Pd(OAc)2fI'PPTS catalyst system in supercritical carbon dioxide. The addition of co-solvents such as water and ethylene glycol significantly enhances the rate of reaction without leaching of Pd into the product phase. The reactants/products can be easily se