Multiparameter correlation of the rate of a [2 + 2] cycloaddition reaction versus solvophobicity parameter and normalized polarity parameter in aqueous solutions

Dual-parameter correlations on rate of a

Dual-parameter correlations on rate of an aromatic nucleophilic substitution reaction in aqueous solutions of methanol, ethanol, and propan-2-ol

✍ M. R. Gholami; A. Habibi Yangjeh 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB

Reaction kinetics of 1-chloro-2,4-dinitrobenzene with piperidine was studied spectrophotometrically in aqueous solutions of methanol, ethanol, and propan-2-ol at 25ЊC. The reaction in these solutions is not catalyzed by piperidine. The plots of second-order rate constants of the reaction vs. mole fr