The kinetics of pyridine exchange on truns-[MO,(py),]' have been followed by 'H-NMR in CD,NO, for M = Re, Tc: k298/s-' = (5.5 i 0.1) x 0.04 i 0.02; A H #/kJmol-' = 11 1 f-3, 101 f 9; dSf/JK-'mol-' = +28 \* 10, +68 \* 35. For the ReV complex, pyridine and oxygen exchanges have been measured simultane
Multinuclear NMR study of vanadium(V) complexation with tartaric and citric acids
β Scribed by M.Madalena Caldeira; M.Luisa Ramos; Ana M. Cavaleiro; Victor M.S. Gil
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 289 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0022-2860
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