Multinuclear NMR Referencing
β Scribed by Granger, P.
- Book ID
- 115360725
- Publisher
- Society for Applied Spectroscopy
- Year
- 1988
- Tongue
- English
- Weight
- 265 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0003-7028
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
With The Power And Range Of Modern Pulse Spectrometers The Compass Of Nmr Spec Troscopy Is Now Very Large For A Single Book-but We Have Undertaken This. Our Book Covers The Periodic Table As Multinuclear Spectrometers Do, And Introductory Chapters Are Devoted To The Essentials Of The Nmr Experiment
## Abstract By means of ^27^Al, ^1^H, ^17^O and ^13^C NMR spectroscopy the structure of the methylaluminoxane (MAO) cocatalyst of KaminskyβSinn catalysts was investigated. We have found that the ^27^Al NMR resonance line of MAO is extremely broad at room temperature (Ξ΄ β 60, ΞΟ~1/2~ 50 Β± 10 kHz). A
Accurate referencing of NMR spectra is of vital impor-latter compound is again strongly pH dependent. We have estimated the J factors for these substances (Table 1). Since tance for both reproducibility and correlation of chemical and structural properties to the chemical shift. The task is the geom