Multimode effects and vibronic borrowing

✍ Scribed by P.M. Champion

• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 320 KB
• Volume: 86
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(82)80197-8

✦ Synopsis

The effecls of a large multldunensional viiratlonal subspace on the Herzberg-Teller (H-T) theory of vibronic borrowmg are explored. It is found that under certam cucumstances sgndicant viiromc intensity can be mduced at the O-O transiiion of a weakly allowed electroruc exntation. Complete breakdown of the H-T theory for large polyatomlc systems IS