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Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II)

✍ Scribed by Macgregor, Mairi J.; Hogarth, Graeme; Thompson, Amber L.; Wilton-Ely, James D. E. T.

Book ID: 120196318
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 264 KB
Volume: 28
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om800686f

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## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4