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Multifunctional Poly(N-vinylcarbazole)-Based Block Copolymers and their Nanofabrication and Photosensitizing Properties

✍ Scribed by Wing Yan Tam; Chris S. K. Mak; Alan Man Ching Ng; Aleksandra B. Djurišić; Wai Kin Chan

Book ID
102491767
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
309 KB
Volume
30
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

The synthesis of poly(N‐vinylcarbazole)‐based block copolymers functionalized with rhenium diimine complexes or pendant terpyridine ligands is reported. The copolymers are synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization, and they exhibit interesting morphological properties as a result of the phase separation between different blocks. The rhenium complex polymer block may function as a photosensitizer, while the terpyridine‐containing polymer block can be used as the template for nanofabrication by selective deposition of zinc complexes.

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📜 SIMILAR VOLUMES

Synthesis and Hole-Transporting Property
Synthesis and Hole-Transporting Property of a Novel Poly(N-vinylcarbazole) Copolymer with Metal-Coordination Sites
✍ Atsushi Kimoto; Jun-Sang Cho; Yugo Matsuura; Kimihisa Yamamoto 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB

## Abstract **Summary:** Hole transporting poly(__N__‐vinylcarbazole) copolymers with phenylazomethine dendron units acting as metal ligation sites were synthesized. These polymers possess both hole‐transport and metal‐collecting units with simple __σ__‐bond linkages. Complexation in the phenylazom