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Multielectron Redox Process of Vanadium Complexes in Oxidation of Low-Coordinate Vanadium(III) to Oxovanadium(V) with Dioxygen

✍ Scribed by Oyaizu, Kenichi; Yamamoto, Kimihisa; Yoneda, Kotaro; Tsuchida, Eishun

Book ID: 126774784
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 87 KB
Volume: 35
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic960198h

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## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf