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Multidimensional Configuration-Space Models of the Electronic Factor in Electron Transfer by Superexchange: Implications for Models of Biological Electron Transfer

✍ Scribed by Wells, M. C.; Lucchese, R. R.


Book ID
120405712
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
227 KB
Volume
103
Category
Article
ISSN
1089-5639

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Electron transfer (ET) is treated as a vibrational quantum mechanical problem in a symmetric Born-Oppenheimer (BO) biparabolic potential of Marcus type, where the distance between the energy minima is given by the reorganization energy Ξ» and force constant k. The interaction is characterized by a ga