Multicomponent latex IPN materials: 2. Damping and mechanical behavior

✍ Scribed by R. Hu; V. L. Dimonie; M. S. El-Aasser; R. A. Pearson; A. Hiltner; S. G. Mylonakis; L. H. Sperling

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 269 KB
• Volume: 35
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19970730)35:10<1501::aid-polb4>3.0.co;2-u

✦ Synopsis

The integrals of the linear loss shear modulus vs. temperature (loss area, LA) and linear tan d vs. temperature (tan d area, TA) were characterized for various core/ shell latex particles with synthetic rubber, poly(butadiene-stat-styrene) [P(Bd/S), 90/ 10], and interpenetrating polymer networks (IPN) as the cores. The IPN cores were composed of P(Bd/S) (T g á 070ЊC) and an acrylate based copolymer (T g around 10ЊC) for potential impact and damping improvement in thermoplastics. Poly(styrene-stat-acrylonitrile) (SAN, 72/28) was the shell polymer for all these polymers. Under the same loading, for both toughening and damping controls, among the IPN core/shell, blend of separate core/shell, and multilayered core/shell polymers, the IPN core/shell polymers were the best dampers. However, the other core/shell polymers also showed higher LA values than P(Bd/S)/SAN core/shell polymer. A comparison of LA values via a group contribution analysis method was made, the effect of particle morphology and phase continuity on damping being studied. Inverted core/shell latex particles (glassy polymer SAN was synthesized first) showed much higher LA and TA values than normal core/shell ones (rubbery polymer was synthesized first). Models for maximum LA and TA behavior are proposed. The damping property was essentially controlled by the phase miscibility and morphology of the core/shell latex particles. The LA values for each peak in these multiphase materials provided some indication of the several fractional phase volumes.